Thanks again for the answers, Afroakuma! I've been considering using Planescape's cosmology for my 3.5/PF games, but I wanted to try and fit it with 3.5's base cosmology as best as possible. Shadow always stroke me as a hard nut to crack, being a demiplane back in 2E and promoted to full transitive plane in 3E. But tying up the Shadow with the Phlogiston not only has a flavor of "backwards compatibility", it also works to bring Spelljammer to the fold. Alas, to work the way I envisioned it, I'd have to hammer Spelljammer and change the way it worked a little bit, since the bit I remembered about the winter glass balls was really real. Not a huge problem by any accounts, but it doesn't hurt to try and find a better way.
Also, by fitting Shadow that way, I couldn't find space for a Plane of Faerie. I wanted to do something like MoP's Spirit World crossed with 4E's Feywild, but then I'd have to find space for
yet another transitive plane. ...Ack, shouldn't have read 4E material
)