next major innovation is the precussion cap, which replaced the small pan of powder (which was the major cause to misfires in flintlocks, as the powder here either failed to ignite or went off without setting off the main charge, a "flash in the pan") with a small 'cap' of precussion (shock) sensitive explosive (orginally, they tried to replace the whole powder charge, but the results were too unstable and shock sensitive for practical use, so they lowered the charge and created the cap). this, again, made the weapon quicker to load and more reliable, and was adotped around the 1840-1860 era, along with rifled barrels, leading to the change from flintlock mustkets to precussion rifles used in the Crimean and Amerian Civil wars.
Here is a video that shows both the loading of a precussion rifles and a civil war era cannon (which is basically the same as napoleonic era cannons, i believe).