A 442 No.

It's actually worse than that. Not only isn't the feat's skill point multiplied at 1st level, you also can't use that single skill point. In both the character creation process (Player's Handbook, page 6) and Level Advancement steps (Player's Handbook, pages 58-59) you spend skill points before you acquire feats. Because it's already too late to spend skill points at the time you gain a feat, and unused skill points do not accumulate, the skill point gained when you take Nymph's Kiss cannot be spent.