Look into the character Hank Scorpio from The Simpsons. He's a supervillain who's super generous and friendly to the employees at the facility where he's building his death laser. The episode he's in ends with a parody of the Goldfinger theme that's all about how good the employee benefits are at his organization.

Also check out the Head Head-Vampire from the Billy and Mandy episode Billy and Mandy Save Christmas. "You will always have a special place in my heart. And in the new world order."